Ni addition induced modification of structural, magnetic properties and bandgap of Ni-Zn nano ferrites

R. Verma (1) , Frédéric Mazaleyrat (2, 1) , U.P. Deshpande (1) , S.N. Kane (1)

1 IITI - Indian Institute of Technology Indore
2 SATIE - Systèmes et Applications des Technologies de l'Information et de l'Energie

We report synthesis, characterization of Zn1-xNixFe2O4 (x = 0.0–1.0) nano ferrites, by using x-ray diffraction 'XRD', vibration sample magnetometery, UV–Vis spectroscopy. XRD validates the formation of fcc spinel structure. Ni-addition leads to: grain diameter modification; linear decrease of lattice parameter; un-equal distribution of both Ni2+, Zn2+, Fe3+ ions on A, B sites; changes in the degree of inversion, and oxygen parameter showing changes in disorder; linear variation of bandgap; significant reduction of coercivity with simultaneous increase of saturation magnetization. Results clearly demonstrate that Ni-addition in Ni-Zn ferrite can be effectively used to tune magnetic properties, bandgap.

Domaines: Chimie

R. Verma, Frédéric Mazaleyrat, U.P. Deshpande, S.N. Kane. Ni addition induced modification of structural, magnetic properties and bandgap of Ni-Zn nano ferrites. Materials Today: Proceedings, 2020, 32 (3), pp.329-333. ⟨10.1016/j.matpr.2020.01.489⟩. ⟨hal-03821228⟩